produktbeskrivelse

Benzylbenzoat Grunnleggende informasjon

Description References

Produktnavn:	Benzyl benzoate
Synonyms:	N-tert-Butoxycarbonyl-L-aspartic Acid αBenzyl benzoate ReagentPlus(R), >=99.0%;Benzyl benzoate Vetec(TM) reagent grade, 98%;Benzoic acid benzyl ester≥ 99% (GC);VANZOATE(R);VENZONATE(R);Benylate;Benzyl alcohol benzoic ester
CAS:	120-51-4
MF:	C14H12O2
MW:	212.24
EINECS:	204-402-9
Produkt kategorier:	Løsemiddel; UORGANISKE OG ORGANISKE KJEMIKALIER; Kjemiske -; Aromatiske estere; Piperazin-derivater; organiske kjemiske stoffer; Byggesteiner; C12 til C63; Karbonylforbindelser; Kjemisk syntese; Estere; Ernæringsforskning; Organiske byggesteiner; Fytokjemikalier etter plante (mat / krydder / urt Vaccinium macrocarpon (Tranebær); CYSTADANE
Mol File:	120-51-4.mol

Benzyl benzoate Chemical Properties

Smeltepunkt	18 °C
Boiling point	323-324 °C(lit.)
density	1.118 g/mL at 20 °C(lit.)
vapor pressure	1 mm Hg ( 125 °C)
brytningsindeks	n20/D 1.568(lit.)
FEMA	2138 \| BENZYL BENZOATE
FEMA	2797 \| OCTANAL
Fp	298 ° F
storage temp.	2-8 ° C
solubility	Miscible with ethanol, alcohol, chloroform, ether, oils.
form	Væske
farge	Klar fargeløs
Water Solubility	practically insoluble
JECFA-nummer	24
Merck	14,1127
BRN	2049280
Stabilitet:	Stable. Substances to be avoided include strong oxidizing agents. Combustible.
InChIKey	SESFRYSPDFLNCH-UHFFFAOYSA-N
CAS DataBase Referanse	120-51-4 (CAS DataBase Reference)
NIST Chemistry Reference	Benzylbenzoat (120-51-4)
EPA Substance Registry System	Benzylbenzoat (120-51-4)

Benzylbenzoat Sikkerhetsinformasjon

Hazard Codes	Xn,N
Risk Statements	22-51 / 53
Sikkerhetserklæringer	25-61-46
RIDADR	UN 3082 9 / PGIII
WGK Germany	2
RTECS	DG4200000
Selvantennelsestemperatur	896 °F
TSCA	Ja
HazardClass	9
HS kode	29163100
Data om farlige stoffer	120-51-4(Hazardous Substances Data)
Toxicity	LD50 in rats, mice, rabbits, guinea pigs (g/kg): 1.7, 1.4, 1.8, 1.0 orally (Draize)

Benzyl benzoate Usage And Synthesis

Beskrivelse	Benzylbenzoat (BnBzO) er et mediasjons- og insektmiddel. Det er en av de eldre preparatene som brukes til å behandle skabb, som er hudinfeksjoner forårsaket av tematisk scarcoptes scabiei, siden det er dødelig for midd. Den er i stand til å drepe midd på 5 minutter. Det kan også brukes til behandling av lusinfestasjon av hodet og kroppen. Virkningsmekanismen er å utøve giftig effekt på nervesystemet til insektene, noe som ytterligere forårsaker dens død. Det er også giftig å midd egg via en ukjent mekanisme. Den kan også brukes som et frastøtende middel for chiggers, flått og mygg, så vel som en fargestoffbærer, løsningsmiddel av cellulosederivater, myknere og et fiksativ.
Beskrivelse	Benzyl benzoate is the ester of benzyl alcohol and benzoic acid, with the formula C6H5CH2O2CC6H5. This easily prepared compound with a mild balsamic odor has a variety of uses.
Kjemiske egenskaper	Benzyl Benzoate is the main component of Peru balsam oil. It occurs in fairly large amounts in a number of blossom concretes and absolutes (e.g., tuberose and hyacinth). It forms either a viscous liquid or solid flakes (mp 21–22°C) and has a weak, sweet, balsamic odor. It is prepared either by transesterification of technical methyl benzoate with benzyl alcohol or from benzyl chloride and sodium benzoate. A third process starts with benzaldehyde, which is converted in high yield into benzyl benzoate in the presence of sodium or aluminum benzylate (Tishchenko reaction). Benzyl benzoate is used in perfumery as a fixative and as a modifier in heavy blossom fragrances.
Kjemiske egenskaper	Colourless oily liquid with pleasant aromatic odour
Kjemiske egenskaper	Benzyl benzoate is a clear, colorless, oily liquid with a slightly aromatic odor. It produces a sharp, burning sensation on the tongue. At temperatures below 178℃ it exists as clear, colorless crystals.
Kjemiske egenskaper	Benzyl benzoate has a light, balsamic odor reminiscent of almond and a sharp, pungent taste.
Bruker	benzyl benzoate is an anti-microbial. It can also act as a solvent, helping dissolve other substances in the product, and as a perfuming ingredient. It is the ester of benzyl alcohol and benzoic acid.
Bruker	antiarteriosklerotisk, hypolipemisk, hepatoprotectant
Bruker	Benzyl Benzoate has seen use as an insecticide, as well as a solvent for various chemical reactions.
Bruker	Used to kill lice and the mites responsible for the skin condition scabies.
Bruker	As solvent of cellulose acetate, nitrocellulose and artificial musk; substitute for camphor in celluloid and plastic pyroxylin Compounds; perfume fixative; in confectionery and chewing gum flavors.
Production Methods	Benzyl benzoate is a constituent of Peru balsam and occurs naturally in certain plant species. Commercially, benzyl benzoate is produced synthetically by the dry esterification of sodium benzoate and benzoyl chloride in the presence of triethylamine or by the reaction of sodium benzylate with benzaldehyde.
Preparation	By the dry esterification of sodium benzoate and benzoyl chloride in the presence of triethylamine or by reaction of sodium benzylate on benzaldehyde.
Merkenavn	Farmasøytisk nødvendighet for Dimercaprol [Injeksjon]. Benylate (Sterling Winthrop).
Taste threshold values	Taste characteristics at 30 ppm: balsamic, fruity with powdery and berry nuances.
Hazard	Irritant to eyes, skin.
Kontakt allergener	Benzyl benzoate is the ester of benzyl alcohol and benzoic acid. It is contained in Myroxylon pereirae and Tolu balsam. It is used in acaricide preparations against Sarcoptes scabiei or as a pediculicide. Direct contact may cause skin irritation, but rarely allergic contact dermatitis. As a fragrance allergen, benzyl benzoate has to be mentioned by name in EU cosmetics.
Kjemisk syntese	This colorless liquid is formally the condensation product of benzoic acid and benzyl alcohol. It can also be generated from benzaldehyde by the Tishchenko reaction.
Oppbevaring	Benzylbenzoat er stabilt når det oppbevares i tette, godt fylte, lett motstandsdyktige beholdere. Eksponering for overdreven varme (over 408â „ƒ) bør unngås.
Uforlikeligheter	Benzyl benzoate is incompatible with alkalis and oxidizing agents.
Regulatory Status	Included in the FDA Inactive Ingredients Database (IM injections and oral capsules). Included, as an active ingredient, in nonparenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.

Benzylbenzoat Tilberedningsprodukter og råvarer

Råvarer	Sodium -> Sodium carbonate -> Triethylamine -> Benzaldehyde -> Benzyl alcohol -> Benzoic acid -> Sodium benzoate -> Ethyl benzoate -> Peru balsam
Preparation Products	3-fenoksybenzylalkohol -> 2,6-dikloranilin -> 4-cyanofenol -> Batylalkohol -> Butetamin -> Disperse Yellow 126